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Groundwater Investigation and Associated Source Characterization

Table 7.4-6 - Calculated versus Exempted Emission Rates

Chemical Compound

Soil gas conc. (ppmv)

Air Displacement (SCFM)

Molecular Weight (lb/lb-mole)

Calculated emission rate

L (mg/M3)

E - Exempted emission rate (lb/hr)

(lb/hr)

(tons/yr)

TCE

480

80

131.4

0.79

3.5

135

16.875

DCE

250

80

97.0

0.31

1.34

79

9.8750

Vinyl chloride

16

80

62.5

0.13

0.59

2

0.25

The equation for estimating emission rate from the SVE is as follows:

Chlorinated hydrocarbon emission rate (lb/hr) = (contaminant concentration) x (contaminants molecular weight in lb/lb-mole) x (air pump rate in cfm) x (1.581 x 10-7 lb-mole-min/ft3-ppmv-hr).  For calculation of yearly emission rates, it was assumed that the SVE system will operate 24 hours a day, 7 days a week, 52 weeks per year at the 30 minute soil gas concentrations.