[CSSA Home]

Groundwater Investigation and Associated Source Characterization, June 1996

Table of Contents

Acronyms and Abbreviations

Section 1 - Introduction

1.1   Purpose of Report

1.2   Regulatory Basis

1.3   Project Authorization

1.4   Investigation Objectives and Scope

1.4.1   Preliminary Evaluation

1.4.2   Source Characterization

1.5   Report Organization

Section 2 - Background

2.1   Facility Description

2.2   Site Background and History

2.3   Chronology

2.4   Environmental Setting

2.4.1   Climate

2.4.2   Topography

2.4.3   Drainage and Surface Waters

2.4.4   Soils

2.4.5   Geology

2.4.6   Hydrogeology

Section 3 - Methodology

3.1   Surface Geophysical Surveys

3.1.1   Electromagnetic Induction

3.1.1.1   Determination of Data Grids

3.1.1.2   Data Collection

3.1.1.3   Data Processing

3.1.2   Ground Penetrating Radar Survey

3.1.2.1   Equipment Specifications

3.1.2.2   Data Collection

3.1.2.3   Data Interpretation

3.1.3   Seismic Reflection

3.1.3.1   Data Collection

3.1.3.2   Downhole Velocity Survey

3.1.3.3   Data Interpretation

3.2   Soil Borings

3.2.1   Drilling

3.2.2   Plugging

3.3   Geophysical Borehole Logging

3.3.1   Logging of Existing Water Wells

3.3.2   Logging of Lower Glen Rose Pilot Holes

3.4   Well Upgrades

3.5   Well Installation Methodology

3.5.1   Vapor Monitoring Points

3.5.2   Vapor Extraction Wells

3.5.3   Groundwater Monitoring Wells

3.5.3.1   Drilling of Pilot Holes and Well Boreholes

3.5.3.2   Monitoring Well Construction

3.5.3.3   Surface Completions

3.5.3.4   Monitoring Well Development

3.6   Well Plugging

3.6.1   Plugging of CSSA Inactive Water Wells

3.6.2   Plugging of Tank Monitoring Wells

3.6.3   Plugging of Pilot Hole 1

3.7   Land Surveying

3.8   Soil Vapor Extraction Test Procedures

3.8.1   Site Layout

3.8.2   Construction of Test System

3.8.3   Air Permeability Test

3.9   Sampling

3.9.1   General Sample Handling Procedures

3.9.2   Soil Gas Field Screening

3.9.2.1   Soil Gas Survey

3.9.2.2   SWMU B-3 Soil Gas Sampling

3.9.3   Soil Gas Emission Testing

3.9.4   Soil/Rock

3.9.5   Groundwater Monitoring and Sampling

3.9.5.1   Groundwater Monitoring Actions

3.9.5.2   Discrete Interval Sampling During Packer Tests

3.9.6   Solid Waste

3.10 Decontamination Procedures

3.10.1   Downhole Decontamination

3.10.2   Decontamination of Sampling Equipment

3.11   Management of Investigation-Derived Waste

3.12   Chemical Analysis

3.12.1   Soil Gas

3.12.1.1   Analytical Equipment

3.12.1.2   Target Compounds and Calibration

3.12.1.3   Target Compound Identification and Quantification

3.12.1.4   Detection Limits

3.12.2   Soil/Rock

3.12.3   Groundwater

3.12.4   Waste Characterization

3.13   Geotechnical Analysis

3.14   Quality Assurance/Quality Control

3.14.1   General Procedures

3.14.2   Soil Gas Quality Control Procedures

3.14.2.1   Sampling Quality Control Procedures

3.14.2.2   Analytical Quality Control Procedures

3.15   Data Validation

Section 4 - Preliminary Assessment

4.1   Records Review

4.2   Water Well Inventory and Surveying

4.3   Groundwater Sampling and Analysis

4.4   Downhole Camera Survey

4.5   Geologic Survey

4.6   Deliverables

Section 5 - Characterization of Potential Source Areas

5.1   Surface Geophysical Surveys

5.2   Drilling and Sampling of Soil Borings

5.2.1   Drilling

5.2.2   Analytical Results

5.2.2.1   Volatile Organic Compounds

5.2.2.2   Metals

5.2.3   Summary

5.2.4   IDW Characterization

5.3   Soil Gas Surveys

5.3.1   Reconnaissance Survey

5.3.2   Detailed Survey

5.3.3   Results and Conclusions

Section 6 - Oxidation Pond Characterization

6.1   Overview

6.2   Characterization Activities

6.2.1   Summary of Liner Integrity Investigation

6.2.2   Characterization and Analytical Results

6.2.3   IDW Characterization

6.3   Identification and Screening of Remedial Alternatives

6.3.1   Viable Alternatives

6.3.1.1   Soil/Rock Washing

6.3.1.2   High Temperature Thermal Desorption

6.3.1.3   Electrokinetics

6.3.1.4   Soil Vapor Extraction

6.4   Summary and Conclusions of SWMU O-1 Characterization

Section 7 - SWMU B-3 Characterization

7.1   Overview

7.2   Characterization Activities

7.3   Study Layout

7.4   SVE Pilot Test and Characterization Results

7.4.1   Site Geology

7.4.2   Soil Sampling Results

7.4.2.1   Volatile Organic Compounds

7.4.2.2   Inorganic Compounds

7.4.2.3   Miscellaneous and Physical Data

7.4.2.4   Delineation of Volatile Organic Compounds

7.4.2.5   Delineation of Metal Contamination

7.4.3   Initial Soil Gas Chemistry

7.4.4   Air Permeability Test Results

7.4.5   Subsurface Influence Findings

7.4.5.1   Findings From Air Permeability Test Results

7.4.5.2   Soil Gas Chemistry Comparison

7.4.5.3   Multiple Configuration Testing

7.4.6   Air Emission/Mass Removal Summary

7.4.6.1   Contaminant Mass Removal Estimates

7.4.6.2   Air Exemption Summary

7.4.7   Investigation Derived Waste Characterization

Section 8 - Hydrogeologic Investigation

8.1   Initial Evaluation

8.1.1   Geophysical Well Logging

8.1.2   Discrete Interval Sampling in Perched Zones

8.1.3   Well Upgrades and Plugging

8.1.3.1   Water Well Upgrades

8.1.3.2   Water Well Plugging

8.1.3.3   Tank Monitoring Wells Plugging

8.2   Groundwater Monitoring

8.2.1   Summary of Quarterly Groundwater Monitoring Events

8.2.2   Well 16 Packer Test

8.2.2.1   Summary of Test and Results

8.2.2.2   IDW Characterization and Disposal

8.2.3   Well 11 Pump and Piping Removal

8.2.4   Well 16 Transducer and Weather Station

8.3   Geologic Investigation

8.3.1   Geologic Mapping

8.3.1.1   Field Mapping

8.3.1.2   Results

8.3.2   Ground Penetrating Radar Profiling

8.3.3   Seismic Reflection Survey

8.3.4   Interpretation of Area Well Logs

8.3.5   Geologic Investigation Results

8.4   Lower Glen Rose Monitoring Well Installation

8.4.1   Pilot Hole Drilling

8.4.2   Logging of Drill Core and Cuttings

8.4.3   Downhole Geophysical Logging

8.4.3.1   Field Actions

8.4.3.2   Interpretation of Logs

8.4.4   Monitoring Well Completion

8.4.5   Monitoring Well Development

8.4.6   Monitoring Well Sampling

8.4.6.1   Analytical Results

8.4.6.2   Groundwater Quality

8.4.7   IDW Characterization

8.5   Future Waste Water Disposal

8.6   Summary of Hydrogeologic Investigation

8.6.1   Site Geology

8.6.1.1   Stratigraphy

8.6.1.2   Structure

8.6.2   Site Hydrogeology

8.6.2.1   Groundwater Flow System

8.6.2.2   Groundwater Contamination

Section 9 - Conclusions and Remedial Alternatives

9.1   Source Removal Actions

9.1.1   Oxidation Pond

9.1.2   SWMU B-3

9.2   Groundwater Investigation

Section 10 - References

Appendices

Appendix A   Soil Boring Logs

Appendix B   Pilot Hole Drilling and Downhole Geophysical Logs

Appendix C   Monitoring Well Completion and Development Logs

Appendix D   Well Plugging Records

Appendix E   Survey Data

Appendix F   Technical Memorandum on Soil Gas Surveys

Appendix G   Groundwater Monitoring Summary and Associated Actions

Appendix H   Waste Characterization Analytical Results and Disposal Manifests

Appendix I   Surface Geophysical Anomaly Maps

Appendix J   Maps of Chemical Constituent Concentrations at Potential Source Areas

Appendix K   Geologic Data

Appendix L   Well Log Index

Figures

2.1-1   Installation Location Map

2.1-2   Site Map

2.4-1   Topographic Map

2.4-2   Drainage at CSSA

2.4-3   Soils Classification Map

2.4-4   Regional Geologic Map

2.4-5   1992 CSSA Well Location Map

2.4-6   Edwards Aquifer RECHARGE Zones near CSSA

3.5-1   Typical Vapor Monitoring Point Construction Detail

3.5-2   Typical Vapor Extraction Well Construction Detail

3.5-3   Deep Well Completion in the Lower Glen Rose

3.7-1   GPS Control Points

3.8-1   Layout of Installed SVE Pilot Test System, SWMU B-3

3.8-2   Instrumentation Diagram for Installed SVE Blower System, SWMU B-3

3.9-1   Schematic of Soil Gas Sampling Arrangement Using a Tedlar Bag

4   Cross Section B - Bl (Strike Section)

5.1-1   Geophysical Anomaly Summary Map

5.3-1   Soil Gas Survey Location Map

5.3-2   PCE Soil Gas Contour Summary Map (PDF Version)

6.2-1   Anomaly Location Map, SWMU O-1 (Oxidation Pond)

6.2-2   SWMU O-1 Chemical Constituents Greater Than Comparison Concentrations

6.2-3   Detailed Distribution of Tetrachloroethene in Soil Gas at the Oxidation Pond Using Data from both the Summer and Fall of 1995

6.2-4   SWMU O-1 Liner Investigation Location Map

6.2-5   SWMU O-1 Cross-Section

6.4-1   PCE Concentrations Over Time, SWMU O-1 Testing

7.1-1   Anomaly Location Map, SWMU B-3

7.1-2   Chemical Constituents Detected at "Hot Spot" Locations, SWMU B-3

7.1-3   Detailed Distribution of TCE in Soil Gas at SWMU B-3 Using Data Collected in the Fall of   1995

7.1-4   Detailed Distribution of PCE in Soil Gas at SWMU B-3 Using Data Collected in the Fall of 1995

7.1-5   Detailed Distribution of cis-1,2-DCE in Soil Gas at SWMU B-3 Using Data Collected in the Fall of 1995

7.3-1   Locations of VEWs and VMPs at SWMU B-3

7.3-2   East-West Cross-Section, SWMU B-3

7.4-1   CSSA SWMU B-3 SVE Air Contaminant Emission Rates

8.2-1   1996 CSSA Well Location Map

8.2-2   Potentiometric Map Without Airline Measurements (May 1994 and September 1994)

8.2-3   Potentiometric Map Without Airline Measurements (5 December 1994 and 12 December 1994)

8.2-4   Potentiometric Map Without Airline Measurements (19 December 1994 and April 1995)

8.2-5   Potentiometric Map Without Airline Measurements (June 1995 and August 1995)

8.2-6   Potentiometric Map Without Airline Measurements (December 1995 and February 1996)

8.2-7   Potentiometric Map Without Airline Measurements (April 1996)

8.2-8   Well 16 HVO Concentrations Over Time

8.2-9   Well D HVO Concentrations Over Time

8.2-10   Water Levels in Well D During the Lower Glen Rose Packer Test

8.2-11   Water Levels in Well D During the Cow Creek Packer Test

8.2-12   Precipitation and Well 16 Water Level Data (September 1995 - March 1996)

8.3-1   Geologic Survey Coverage

8.3-2   Map of GPR Lines and Interpretations

8.3-3   Areas of Bexar Shale Displacement Interpreted from Seismic Reflection Data

8.3-4   Geologic Map of CSSA

8.4-1   Piper Diagram

8.6-1   Cross-Section A-A' (Dip Section)

8.6-2   Cross-Section B-B' (Strike Section)

Tables

2.3-1   Chronology of Groundwater Investigation

2.4-1   Regional Stratigraphic Units and Their Water-Bearing Properties

4.1-1   Potential Source Areas of Well 16 Contamination

5.1-1   Summary of Geophysical Anomalies Related to Suspected Past Waste Management

5.2-1   Summary of Drilling and Sampling Activities

5.2-2   Potential Source Area Analytes Detected Above Comparison Criteria

5.3-1   Summary of Soil Gas Survey Results

6.2-1   Chemical Constituents Detected in Soil and Groundwater

6.2-2   Analytical Results for O-1 Liner Integrity Test Soil Samples

6.3-1   Preliminary Screening of Remediation Technologies for SWMU O-1 Contaminated Soils

7.1-1   Chemical Constituents of Concern Detected in Soil and Groundwater

7.3-1   Description of Clays of SWMU B-3

7.4-1   Analytical Results for Soil Samples, SWMU B-3

7.4-2   Geotechnical and Physical Property Results of Soil Samples Collected at SWMU B-3

7.4-3   Initial Soil Gas Chemistry, Screening Results, SWMU B-3

7.4-5   Comparison of Initial Soil Gas Chemistry to Soil Gas Chemistry after 95 hours of Air Extraction at VEW-01, SWMU B-3

7.4-6   Calculated versus Exempted Emission Rates

7.4-7   Analytical Results for IDW Associated with the SVE System, SWMU B-3

8.1-1   Analytical Results of Discrete Interval Sampling Above Static Water, September 1994

8.2-1   April 1996 Well Information

8.2-2   Summary of Groundwater Elevations (updated version)

8.2-3   Groundwater HVO Analytical Results for 1995 & 1996

8.2-4   Groundwater Metals Analytical Results , December 1995, February & March 1996

8.2-5   Groundwater HVO Analytical Results for Offsite Wells

8.2-6   Groundwater Metals Analytical Results for Offsite Wells, December 1995

8.2-7   Analytical Results of Purge Water at Well 16

8.3-1   Geologic Unit Thickness Determined by Geophysical Log Interpretation

8.4-1   VOC and Metal Analytical Data for April 1996

8.4-2   Aqueous Phase Constituents in Well Samples

8.4-3   Analytical Results of MW1 and MW2 Purge Water and Decontamination Water

8.6-1   Published and Observed Thicknesses of Geologic Units

9.1-1   Summary of Remedial Alternatives for SWMU O-1

9.1-2   Summary of Remedial Alternatives for SWMU B-3

9.2-1   Summary of Remedial Alternatives for Groundwater Contamination