[Home]

[RFI Report] [Next Section]

SWMU B-9 Final RCRA Facility Investigation/Closure Report

Section 2 - Field Investigation

2.1 - Field Actions

As outlined in the Environmental Encyclopedia site-specific work plan (Volume 1-2, SWMU B-9), project RFI requirements were to conduct a geophysical survey and to collect surface and subsurface soil samples.  SWMU B-9 is an area where miscellaneous solid waste was reportedly disposed.  All field activities were conducted in accordance with the Field Sampling and Analysis Plan (Volume 1-4, Field Sampling Plan and Quality Assurance Project Plan) 

2.1.1    Geophysical Survey

Electromagnetic (EM) and ground penetrating radar (GPR) geophysical surveys were conducted at SWMU B-9 in November 1999 under DO5068.  Prior to collecting EM or GPR data, a grid system was established to encompass the areas of suspected ground disturbance.  This grid consisted of staked locations separated by intervals of 50 feet.  Figure B9-4 illustrates the layout of the geophysical survey grid at SWMU B-9.

EM data were collected at 2-foot intervals along transects that were separated by 10 feet using the established geophysical survey grid.  EM measurements were taken using a Geonics EM31-DL ground conductivity meter and recorded with a Polycorder data logger.  The conductivity meter consists of transmitter and receiver coils that are separated by 12 feet.  The instrument has a nominal depth of penetration of approximately 16 feet when operated in the vertical-dipole mode.  The instrument measures both quadrature- and in-phase components of an induced magnetic field.  The quadrature-phase component is a measure of apparent ground conductivity while the in-phase component is more sensitive to the presence of ferromagnetic metal.  A lateral variation in apparent ground conductivity indicates a lateral change in subsurface physical properties (i.e., related to degree of disturbance).  Apparent ground conductivity is measured with a precision of approximately ±2 percent of the full-scale meter reading, which corresponds to approximately two milliSiemens per meter (mS/m).  The in-phase component of the EM-31 is the response of the secondary to primary magnetic field measured in units of parts per thousand (ppt).  The primary magnetic field is due to the current source from the EM-31.  The secondary magnetic field is due to induced currents within conductive material in the subsurface.

Data was collected by setting the instrument to record in an automatic vertical dipole mode.  Readings were taken at 0.5 second intervals which corresponded to a reading every two feet along a given transect.  Both apparent ground conductivity (i.e., quadrature phase) and in-phase data were recorded.  The operator aligned himself along a transect and, with the instrument parallel to the transect, paced between marked or staked stations separated by 10 feet.

The EM-31 survey was completed according to the procedures described in Volume 1-4, Sampling and Analysis Plan, Section 1.1.2.  Prior to the survey, an area near SWMU B-9 that was determined to be free of disturbances and anomalies was selected and marked to perform background checks and calibration.  The background checks were also performed after the survey.  All calibration data along with before and after background readings were recorded in the field logbook.

GPR is a surface geophysical technique that uses high-frequency EM energy.  Pulses of short-duration EM energy are transmitted into the subsurface from the radar antenna that is moved across the ground surface at a slow and uniform pace.  The radiated energy encounters heterogeneities or anomalies in electrical properties of the subsurface, which causes some energy to be reflected back to the receiving antenna and some to be transmitted downward to deeper material.  The amplitude or strength of the EM energy reflected from subsurface materials depends on contrasts in the electrical properties (conductivity and dielectric constants) of those materials.  The reflected signal is amplified, transformed to the audio-frequency ranges, recorded, processed, and displayed.  Recorded data displays the two-way travel time for a signal to pass through the subsurface, reflect, and return to the surface.

The observed time for the reflected signal to return to the antenna from a subsurface feature is an indication of the depth to the reflector.  The two-way reflection time can be converted to depth if the EM wave velocity of the subsurface soils is known.  In the absence of such information, an approximate time to depth conversion can be estimated by using published values of material velocity for different soil types.

GPR surveys were conducted with a GSSI SIR-2 instrument to verify the information obtained by the EM survey.  Two GPR profiles were created in the northeast-southwest direction and three were created in the southeast-northwest direction (Figure B9-4).  A 300 mega-hertz (MHz) antenna with a range setting of 90 nanoseconds (ns) was used for all profiles.  The survey was conducted in accordance with procedures outlined in Volume 1-4, Sampling and Analysis Plan, DO5068 Addendum, Section 2.4.  The individual GPR survey profiles were conducted over anomalies that were detected during the EM-31 survey.  Additional surveys were also conducted at the site to provide background information.  If no anomalies were identified during the EM‑31 survey, the GPR was used to gather additional background information for the site.

The GPR profiles were sequentially numbered with a GPR profile number as they were created throughout the day.  Therefore, each profile is identified with a sequential number that is not related to the number of profiles created at the site. 

2.1.2    Soil Gas Survey Samples

In accordance with the approved work plan, a soil gas survey was not performed in association with the current investigation conducted for SWMU B-9. 

2.1.3    Surface and Subsurface Soil Samples

In 1996, samples were collected from two borings in an area thought at the time to be SWMU B-9.  It was later determined that these samples were located within the nearby AOC-44, which is approximately 300 feet north.  These samples were analyzed by ITS Laboratory in Richardson, Texas, and were later found to be unusable by the Environmental Protection Agency (EPA) for site closure purposes.  Therefore, in March 2000 rework samples were collected, but they were collected within the SWMU B-9 boundary.

In March 2000, three soil borings were advanced and nine soil samples were collected at SWMU B-9.  These surface and subsurface soil samples were the first collected from SWMU B-9.  The boring locations are shown on Figure B9-5.  Samples collected between zero and one-foot bgs are considered surface soil samples.  Two of the samples were collected as part of the laboratory rework field effort, though no surface soil samples were previously analyzed from SWMU B-9.  The third sample was collected as part of the RL53 DO field effort.  Since the geophysical survey revealed no anomalies, the samples were collected from areas that would provide a general characterization of the site.  The samples were submitted to APPL Laboratories in Fresno, California, for VOC (SW-8260B) and SVOC (SW-8270C) analysis to DataChem Laboratories in Salt Lake City, Utah, for explosives (SW-8330) analysis, and to O’Brien and Gere Laboratories in East Syracuse, New York for metals analysis.  Metals analyses included SW-6010B for barium, chromium, copper, nickel, and zinc; SW-7060A for arsenic; SW-7131A for cadmium; SW-7471A for mercury; and SW-7421 for lead.  A total of nine environmental samples, one field duplicate, one matrix spike, one spike duplicate, and one trip blank were submitted for analysis. 

Samples collected above the bedrock were obtained using a decontaminated hollow-stem auger and split-spoon sampler.  Rock samples were obtained by air rotary methodology using a decontaminated core barrel.  Since no geophysical anomalies were detected, borings were advanced in locations that would accurately characterize the subsurface conditions at SWMU B-9.  Boring depths were determined by the work plan, which called for borehole terminus after drilling through five feet of competent bedrock (Volume 1-1, Work Plans, RL17 Addendum).  All decontamination, sample preparation and handling followed those protocols established in the Field Sampling and Analysis Plan (Volume 1-4, Field Sampling Plan, Quality Assurance Project Plan).  Environmental sampling also included the collection and submittal of QA and QC samples at those frequencies outlined in the AFCEE QAPP (Volume 1-4, Quality Assurance Project Plan). 

A review of the boring logs generated during the subsurface investigation (Appendix B) identifies a thin veneer of soil present at this site.  The SWMU B-9 surface soil samples were loose, dry, silty clays with cobbles.  Materials representative of the Upper Glen Rose Formation were typically encountered at depths of less than one foot bgs.  The Upper Glen Rose was identified to consist of materials varying from limestone to clayey marl.  At the time of sampling, no evidence of contamination was identified either through visual observation or with a photoionization detector (PID) instrument.  Soil boring logs from the borings advanced in 2000 are presented in Appendix C.

2.1.4    Groundwater Samples

In accordance with the approved work plan, groundwater samples were not collected in association with the investigation conducted for SWMU B-9.  Groundwater was not encountered in any of the soil borings.

2.1.5    UXO Sweep

On April 9 and 10, 1997, a UXO sweep was performed by UXO specialists from UXB International, Ashburn, Virginia.  The UXO specialists traversed the site in a systematic manner to visually identify UXO on the surface.  In addition, they used Schonstedt magnetometers to assist in identification of metal at or near the surface.

2.2 - Results and Comparisons

2.2.1    Geophysical Survey

The geophysical surveys revealed no evidence of subsurface anomalies related to past waste disposal activities.  There was little variation in the data that were recorded during the EM survey, which can be interpreted as homogeneous and consistent soil and bedrock profiles throughout SWMU B-9 (Figure B9-6 and Figure B9-7).  In-phase readings during the EM survey ranged from a minimum of –1.537 ppt, to a maximum of 0.836 ppt.  The contour interval in Figure B9-6 is only 0.3 ppt, and the slight variations near SB01, SB02, and SB03 are not considered great enough to be considered anomalies.  Quadrature-phase readings ranged from a low of 12.60 mS/m, to a high of 16.33 mS/m.

The GPR surveys were conducted to further investigate the information obtained by the EM survey.  Like the EM survey, the GPR also revealed no evidence of subsurface anomalies.  The GPR profile included in this report (Figure B9-8) represents the typical 300 MHz antenna survey profile that was produced at SWMU B-9.  Resolution of the profile was poor due to the homogeneous nature of the clay-rich soil and underlying bedrock; however, the shallow dipping bedrock can be seen in the GPR profile.  The vertical scale on the profile, time in ns, can be converted into feet using the following formula:

Range = Depth x Time (ns) x 1.5

Where:

Range = 90 ns for profiles with a 300 MHz antenna.

Depth = depth bgs in feet.

Time = 4.5 ns per foot, this is the value given for dry limestone in the GSSI SIR-2 instruction manual.

According to this equation, the depth that represents 90 ns is 13.3 feet.  The two-way travel time is only an estimate and can vary somewhat from site to site and also within the profile itself.

The interpretation of subsurface conditions is based on analysis of the recorded sections.  Buried objects such as pipes and tanks are usually evident as prominent hyperbolic reflections on the GPR records.  Subsurface soil changes can be difficult to interpret, but often can be discerned as a lateral change in the texture or reflection character of the GPR signal.  Optimal subsurface conditions for use of GPR are dry sandy soils.  The presence of even minor amounts of clay may effectively limit depth of investigation to less than a few feet due to absorption and reflection of the EM energy.  Stratigraphic changes are often very prominent and may affect the GPR readings.  The use of GPR to determine landfill boundaries and buried waste disposal trenches can be at times very successful due to contrasts in reflection character between the natural stratigraphy outside the trench boundaries and the disturbed soils within the disposal areas.

The interpretation of subsurface conditions is based on analysis of the recorded sections.  Buried objects such as pipes and tanks are usually evident as prominent hyperbolic reflections on the GPR records.  Subsurface soil changes can be difficult to interpret, but often can be discerned as a lateral change in the texture or reflection character of the GPR signal.  Optimal subsurface conditions for use of GPR are dry sandy soils.  The presence of even minor amounts of clay may effectively limit depth of investigation to less than a few feet due to absorption and reflection of the EM energy.  Stratigraphic changes are often very prominent and may affect the GPR readings.  The use of GPR to determine landfill boundaries and buried waste disposal trenches can be at times very successful due to contrasts in reflection character between the natural stratigraphy outside the trench boundaries and the disturbed soils within the disposal areas.

2.2.2    Soil Gas Survey Samples

In accordance with the approved work plan, a soil gas survey was not performed in association with the investigation conducted for SWMU B-9.

2.2.3    Surface and Subsurface Soil Samples

As described in Section 2.1.3, a total of nine samples (and one duplicate) were collected for analysis at SWMU B-9.  RRS1 exceedances, which include those above background levels for metals and above RLs for organics and explosives, were very limited.  Metals concentrations were only slightly above background in two Glen Rose samples, dichlorodifluoromethane was detected above the RL in eight of the samples, and toluene and methylene chloride were each above the RL in one sample.  No SVOCs or explosives were detected above project RLs in any of the samples that were collected at SWMU B-9.  Analytical data are summarized in Table B9-1, and a complete list of analytical results is provided in Appendix A.  Background metals levels were statistically calculated for CSSA soils and the Glen Rose Limestone, and are reported in the Second Revision to the Evaluation of Background Metals Concentrations in Soils and Bedrock at CSSA (Parsons, February 2002).

Zinc concentrations were identified at 14.3 milligrams per kilograms (mg/kg) in sample B9-SB02 (7.5-8.0 ft) and at 22.3 mg/kg in sample B9-SB03 (5.0-5.5 ft).  Both detected concentrations exceeded the RRS1 criteria for CSSA Glen Rose limestone of 11.3 mg/kg, but were below the Texas-specific median background concentration of 30 mg/kg (30 TAC 350.51(m)).

Mercury was reported at 0.2 mg/kg in sample B9-SB02 (7.5-8.0 ft).  This concentration exceeded the RRS1 criteria for CSSA Glen Rose limestone of 0.1 mg/kg, but the value is below the most conservative protective concentration level (PCL) for residential soils in a 0.5-acre area for mercury (2.1 mg/kg). 

Dichlorodifluoromethane was detected above RRS1 values in eight subsurface soil/rock samples.  The only sample that did not contain a concentration of dichlorodifluoromethane that exceeded the RRS1 standard was B9-SB03 (0.5-1.0 ft).  The highest concentration of dichlorodifluoromethane, 0.038 mg/kg, was reported in B9-SB01 (3.0-3.5 ft).  This value exceeded the RRS1 value of 0.005 mg/kg.  All concentrations detected above RRS1 standards were below the most conservative PCL for residential soils in a 0.5 acre area of 240 mg/kg. 

Methylene chloride was detected above RRS1 soil/rock criteria in only one of the samples [B9-SB03 (0.5-1.0 ft)].  The detected concentration of 0.0055 mg/kg slightly exceeded the RRS1 standard (practical quantitation limit [PQL]) of 0.005 mg/kg.  This concentration was below the most conservative PCL for residential soils in a 0.5 acre area of 0.013 mg/kg. 

Toluene was detected above RRS1 standards in sample B9-SB02 (0.5-1.0 ft).  A concentration of 0.0074 mg/kg was detected and exceeded the RRS1 standard (PQL) of 0.005 mg/kg.  This value was below the most conservative PCL for residential soils in a 0.5 acre area for toluene of 8.2 mg/kg. 

2.2.4    Groundwater Samples

As stated in Section 2.1.4, groundwater samples were not collected in association with the investigation conducted for SWMU B-9. 

2.2.5    UXO Sweep

The UXO sweep conducted on April 9 and 10, 1997 focused on the southeastern portion of the East Pasture where SWMU B-9 is located.  Several pieces of UXO were discovered and removed during this effort.  The UXO items were found in areas north of SWMU B-9.  No UXO was found at SWMU B-9, only small scrap metal fragments that were scattered across the site.

[Next Section]